What is the Silver Mirror Test? Silver Mirror Test is a test that is used to differentiate between aldose and ketose sugars using the Tollen's reagent. Tollen's reagent is an alkaline solution of ammoniacal silver nitrate and is used to test for aldehydes. *Ketones do not react with the Tollen's reagent. Silver ions in the presence of hydroxide ions form a brown precipitate of silver (I) oxide, Ag 2 O (s) . Ag 2 O This precipitate dissolves in aqueous ammonia, forming the diamminesilver(I) ion, [Ag(NH 3 ) 2 ] + . The reactions that take place in this experiment are as follows: 2Ag + (aq) + 2OH - (aq) → Ag 2 O (s) + H 2 O (l) Ag 2 O (s) + 4NH 3 (aq) + H 2 O (l) → 2[Ag(NH 3 ) 2 ] + (aq) + 2OH - (aq) What happens if Silver Nitrate is used without ammonia or why is ammonia used in this experiment? When ammonia is added to the silver nitrate solution, silver ions are less prone to re...