When a p-n junction is forward biased, free electrons move through the junction and recombine with holes. The energy of a free electron (E1) is greater than that of a bonded electron (E2).
Thus it should be clear that during the recombining process, some energy is released. In a usual silicon diode, this energy is given out as heat.
However when we change the manufactured material, this energy in some occasions is converted or given out as light. When a free electron recombines with a hole in such materials, the light energy is released as photons.
The energy of such a photon is given by E1 - E2 = hc / λ. Here E1 - energy of a free electron, E2 - Energy of a bonded or recombined electron, h - Planck's constant, c- speed of light and λ - wave length.
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Various colored light can be obtained by using various compounds to manufacture the semiconductor materials. The color of such LEDs depends upon the conductive substance used, the chemical composition of the substance and the doping concentration.
For example, Indium gallium nitride (InGaN) is used to make up the blue, white, true green, and UV types.
Aluminum gallium indium phosphide (AlGaInP or AlInGaP) is used to make the red, yellow, and orange types.
For easy recognition, the anode in any LED is produced to be longer than that of the cathode.
Usually a current of 10 mA and a forward biased voltage of 1.5v - 2.5v is necessary to light such a diode. If a LED is connected to a circuit that is provided with a higher voltage than the value specified above, a safety resistor (Rs) should be connected to the circuit.
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If the supplied/input voltage is Vs, the potential difference across the LED is Vd and the current that flows through the LED is Is, then from Ohm's law
Vs - Vd = Is Rs
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